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the allowed quantum states Statistical mechanics provides the means for arriving at the proper average value The fundamental postulate of statistical mechanics for a system of given volume in equilibrium with surroundings at fixed temperature is that the probability of a quantum state depends only on its energy, and all quantum states with the same energy have the same probability A value for the thermodynamic internal energy is found as the average of the energies of the accessible quantum states, each weighted by its probability The quantity of fundamental importance to come out of this procedure is the partition f ~ n c t i o n : ~

where Ei is the energy of level i , gi is the degeneracy of the level, and k is Boltzmann's constant This quantity is a state function, from which all thermodynamic properties may be found once it is known as a function of T and V In particular, the internal energy is given by:

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Equations (1613) and (1614) are written for the total energy of a macroscopic system The problem of their application is greatly simplified for ideal gases, which (because of the absence of molecular interactions) do not possess intermolecular potential energy The internal energy of ideal gases is therefore associated with individual molecules, and results from translation and rotation of each molecule as a whole and from rotations and vibrations internal to the molecule Energy is also associated with the electrons and nuclei of atoms For ideal gases all of these forms of energy are usually treated as separable, and this allows the partition function to be factored and written as a product of partition functions, each of which relates to a particular form of molecular energy It suffices for present purposes to treat the translational kinetic energy as separable from all other contributions These other contributions together constitute the intramolecular energy of a molecule, and they depend on molecular structure We therefore write:

While statistics are Run to Daylight, p 78 Keep in mind that From undated Vince Lombardi talk entitled Goal Posts, in Vince Lombardi, Jr s collection The ego destroys From a speech delivered by Vince Lombardi at the Fathers-Sons Communion Brunch at St Bonaventure Prep, Sturtevant, Wisconsin, 4/16/67, but also in Vince Lombardi s 5/64 speech to the First Friday Club in Los Angeles Whatever the reasons Winning is a Habit, p 134 If I ever hear Maraniss, David When Pride Still Mattered Simon & Schuster, Inc New York: 1999, p 241 I ll never absolutely never Vince, p 266 If you re black or white Vince, p 265 Why, he asked his golfing buddies Winning is a Habit, p 242 Every year I try Strive to Excel, p 53; Vince, p 262

An equilibrium mixture of the reactants is placed in a sealed container at 150 C The amount of the products may be increased by which of the following changes I raising the temperature of the container II increasing the volume of the container III adding 1 mol of C(s) to the container (A) II only (B) I and II (C) I only (D) II and III (E) III only

whence In these equations the quantity N! arises because in the summation process the molecules are treated as distinguishable from one another, whereas in fact they are indistinguishable The translational contribution comes from kinetic theory, whereas the intramolecular contributions derive from quantum mechanics, with the quantized energy levels determined from appropriate spectroscopic measurements

he name implies a sum over states partitioned according to energy levels, and the symbol comes from the German word, Zustandssumme, sum-over-states The other commonly used symbol is Q, which is used in this book to represent heat

Work and sacrifice Strive to Excel, p 134; Vince Lombardi s 6/22/70 Dayton speech Improvements in moral From an undated Vince Lombardi talk entitled Goal Posts, in Vince Lombardi, Jr s collection Hell, I m an emotional man Sports Illustrated There s nothing personal Strive to Excel, p 96; quoted from Second Effort, a sales-training film produced by the Dartnell Corporation, Chicago Once you agree Strive to Excel, p 95 Every vocation calls From an undated Vince Lombardi talk entitled Goal Posts, in Vince Lombardi, Jr s collection When I speak of Spartanism This version is from a speech delivered by Vince Lombardi at the Fathers-Sons Communion Brunch at St Bonaventure Prep, Sturtevant, Wisconsin, 4/16/67, but there s a close approximation in The Speech, the 6/22/70 Dayton speech, and others The only way I know Run to Daylight, p 24 Everything with him is Coach, p 329

For one mole of an ideal gas, the equation for the translational partition function is:''

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